This is an amazing find!!!
From my own research I've divided Duke's development into few significant stages we know about/seen:
In general:
- lameduke
- duke beta from the .pcx screenshots presspacks (jumpsuit troopers etc.)
- late beta - double barrel shotgun pigcops, generally looking very close to final
- The close final betas (0.99 and later?) with available executables (minor differences)
It seems, that the shot from the page you've posted actually fall between phases 1 & 2 (closer to 2 I guess but still) so it's kinda transitional:
- both the kick from final duke and the wrench/taser from lameduke appear, with kick looking different - #2 features either the final kick graphic or a close variant
- Lameduke pistol but #2 pigcops - #2 screenshots feature the final pistol
- Lameduke rocketlauncher, but seems to me that it might be the cleaned up version from phase #2 (dithered color gradients etc.) - the scan is grainy, so I'm guessing
- Barcode still visible on the hand - #2 removed the barcode
- A hud which is seen nowhere else! However it seems close in design to Lameduke's and close in color scheme to #2 hud
I've sandwiched the scanned shots between the #2 shots to demonstrate


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